熊本大学 大学院自然科学研究科 理学専攻 有機化学 西野研究室

RESEARCH OVERVIEW

Study of Free-Radical Cyclization of Organic Compounds Using Transition-Metal Complexes

 

Synthesis of basic structures derived from naturally occurring products such as macrodiolides, cyclophenes, 1,2-dioxan-3-ols, lactones, furans, 4,5-dihydrofurans, and bicyclic and tricyclic compounds and Elucidation of the reaction mechanism
 

Study of Metal-Catalyzed Oxidation of Organic Molecules

 
Synthesis of epoxides, substituted 4,4'-biphenyldiols and 4,4'-diphenoquinones and, Mechanistic study

 

Study of the Carbon-Carbon Bond Formation under High Pressure

 
Direct diacetylmethylation of aromatic compounds
 

Study of Photo-Induced Intramolecular Cyclization and Photooxygenation of Organic Compounds


Synthesis of substituted naphthalenes and oxiranes
 

Study of Separation and Total Synthesis of Natural Products

 
Synthesis of 2-aryl-4(1H)-quinolinones, quinolines, pyrrolo[1,4]benzodiazepine antibiotics and dibenz[b,f]oxepins
 
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LABORATORY INSTRUMENTATION

500MHz Fourier-Transform Nuclear Magnetic Resonance Spectrometer [FT NMR]
300MHz Fourier-Transform Nuclear Magnetic Resonance Spectrometer [FT NMR]
Fourier-Transform infrared Spectrophotometer [FT IR]
Gas Chromatography-Mass Spectrometer [GCMS]
Diode-Array Ultraviolet-visible spectrophotometer [UV-vis]
Polarimeter
Stainless Autoclave(1〜200 atm)・Glass Reactor(1〜15 atm)
Molecular Orbital Calculation System [Spartan'08]
Microwave Reactor
Ozonizer
Gas Chromatography Apparatus [GC]
High Performance Liquid Chromatography Apparatus [HPLC]
 
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